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Tetramethyl tert-butylcalix[4]arene tetraketone

Ferguson, George, Gallagher, John F. orcid logoORCID: 0000-0002-7112-7450 and McKervey, M. Anthony (1993) Tetramethyl tert-butylcalix[4]arene tetraketone. Acta Crystallographica Section C, 49 (3). pp. 602-604. ISSN 0108-2701

Abstract
The title molecule, 25,26,27,28-tetraacetonyloxy-5,11,- 17,23-tetra-tert-butylpentacyclo[19.3.1.13,7.19,13.115,19]- octacosa-1(25),3,5,7(28),9,11,13(27),15,17,19,21,23-dodecaene, has twofold crystallographic symmetry and adopts a distorted cone conformation in the solid state. The orientation of the four aromatic tings is such that two of the rings are almost parallel to each other and the other two almost normal to one another. This conformation precludes a solvent molecule being enclathrated within the cavity.
Metadata
Item Type:Article (Published)
Refereed:Yes
Subjects:Physical Sciences > Organic chemistry
Physical Sciences > Crystallography
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences
Publisher:International Union of Crystallography
Official URL:http://dx.doi.org/10.1107/S0108270192010515
Copyright Information:© 1993 International Union of Crystallography
Use License:This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License
ID Code:3624
Deposited On:20 Mar 2009 16:20 by DORAS Administrator . Last Modified 10 Oct 2018 12:50
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