Gallagher, John F. 
ORCID: 0000-0003-4130-4556 and Murphy, Carol
(1999)
C-H...πarene, Csp³-H...O=C and O-H...O intermolecular interactions in (2R/2S)-3-(3-hydroxyphenyl)-2-(1-oxo-1,3-dihydro-2H-isoindol-2-yl)propanoic acid: a meta-tyrosine derivative.
Acta Crystallographica Section C, 55
(12).
pp. 2167-2169.
ISSN 0108-2701
Abstract
The title compound, C₁₇H₁₅NO₄, a DL-meta-tyrosine
derivative forms a hydrogen-bonded network in
the solid state which consists of Oacid--H... Ophenyl--H...O=Cisoindole chains [O...O 2.668 (2) and
2.653 (2)Å], Csp³--H ...O=Cacid [C...O 3.225 (3)Å]
and two C--H...πarene intermolecular interactions.
The Carene--H...πphenyl interaction is short, C...Cg
3.542(3)Å, where Cg is the phenyl ring centroid
(H...Cg 2.64 Å and C--H...Cg 165°). The interplanar
angle between the five- and six-membered rings of the
isoindole system is 0.95 (13)° with the carbonyl-O atom
0.096(3)Å from the C₄N ring plane. π-π stacking
involving inversion symmetry-related isoindole groups
occurs with RS pairs (interplanar distance of 3.43 Å).
Metadata
| Item Type: | Article (Published) |
|---|---|
| Refereed: | Yes |
| Subjects: | Physical Sciences > Chemistry Physical Sciences > Crystallography |
| DCU Faculties and Centres: | DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences |
| Publisher: | International Union of Crystallography |
| Official URL: | http://dx.doi.org/10.1107/S0108270199010884 |
| Use License: | This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License |
| ID Code: | 299 |
| Deposited On: | 12 Mar 2008 by DORAS Administrator . Last Modified 10 Oct 2018 12:34 |
Documents
Full text available as:
Preview |
PDF
- Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader
343kB |
Downloads
Downloads
Downloads per month over past year
Archive Staff Only: edit this record