Gallagher, John F. 
ORCID: 0000-0003-4130-4556, Kenny, Peter T.M. ORCID: 0000-0002-7112-7450 and Sheehy, Michael J.
(1999)
Intramolecular C-H...O and intermolecular N-H...O and C-H...O interactions in N-ferrocenoylglycine benzyl ester, an effective dihydrogen phosphate anion sensing agent.
Acta Crystallographica Section C, 55
(8).
pp. 1257-1260.
ISSN 0108-2701
Abstract
The title compound, benzyl N-(ferrocenecarbonyl)glycinate,
[Fe(C₅H₅)(C₁₅H₁₄NO₃)], a glycine benzyl ester derivative, is an effective anion sensor for electrochemically sensing the dihydrogen phosphate anion (H₂PO₄-).
Intermolecular N--H...O hydrogen bonds form onedimensional
chains with graph set C(4) [N...O 2.811 (3)Å,]. A two-dimensional network is formed by linking the chains through Car--H...0=Cester interactions about inversion centres [graph set R²₂(14); C...O 3.406 (4)Å]. An intramolecular Ccp-H...0=Cester interaction
[C...O 3.540 (3)Å,] with graph set S(9) completes
the hydrogen bonding.
Metadata
| Item Type: | Article (Published) |
|---|---|
| Refereed: | Yes |
| Subjects: | Physical Sciences > Chemistry Physical Sciences > Crystallography |
| DCU Faculties and Centres: | DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences |
| Publisher: | International Union of Crystallography |
| Official URL: | http://dx.doi.org/10.1107/S010827019900520X |
| Use License: | This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License |
| ID Code: | 297 |
| Deposited On: | 11 Mar 2008 by DORAS Administrator . Last Modified 10 Oct 2018 12:37 |
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