Gallagher, John F. ORCID: 0000-0003-4130-4556, Briody, John M. and Cantwell, Brendan P. (1998) N-H...N Hydrogen Bonding in the Four Independent Molecules of (2S,4S,5R)-(-)-2-(1H-Imidazol-2-yl)-3,4-dimethyl-5-phenyl-1,3-oxazolidine, with C-H...πarene, C-H...O and C-H...πC=C Interactions. Acta Crystallographica Section C, 54 (9). pp. 1331-1335. ISSN 0108-2701
Abstract
The title compound, C₁₄H ₁₇N₃ O, prepared from (1R,2S)-
(-)-ephedrine, crystallizes in space group P2₁ with four
molecules in the asymmetric unit. The molecules, in
pairs, take part in intermolecular N--H...N hydrogen bonding between the imidazolyl rings, forming one-dimensional
chains with alternating N...N distances of
2.866 (3)/2.883(3) and 2.945 (3)/2.956(3)Å. Inter-chain
Carene--H...πarene, Carene--H...O and Csp3--H...πc=
interactions generate a three-dimensional network.
Metadata
Item Type: | Article (Published) |
---|---|
Refereed: | Yes |
Subjects: | Physical Sciences > Chemistry Physical Sciences > Crystallography |
DCU Faculties and Centres: | DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences |
Publisher: | International Union of Crystallography |
Official URL: | http://dx.doi.org/10.1107/S0108270198004089 |
Use License: | This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License |
ID Code: | 291 |
Deposited On: | 11 Mar 2008 by DORAS Administrator . Last Modified 10 Oct 2018 12:35 |
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