Mosnier, Jean-Paul ORCID: 0000-0002-9312-1754, Kennedy, Eugene T. ORCID: 0000-0002-0710-5281, Bizau, J.-M., Cubaynes, Denis, Guilbaud, Ségolène, Blancard, Christophe and McLaughlin, Brendan M. ORCID: 0000-0002-5917-0763 (2021) Photoionization cross-sections of carbon-Like N+ near the K-Edge (390–440 eV). Atoms, 9 (27). ISSN 2218-2004
Abstract
: High-resolution K-shell photoionization cross-sections for the C-like atomic nitrogen ion
(N+
) are reported in the 398 eV (31.15 Å) to 450 eV (27.55 Å) energy (wavelength) range. The
results were obtained from absolute ion-yield measurements using the SOLEIL synchrotron radiation
facility for spectral bandpasses of 65 meV or 250 meV. In the photon energy region 398–403 eV,
1s −→ 2p autoionizing resonance states dominated the cross section spectrum. Analyses of the
experimental profiles yielded resonance strengths and Auger widths. In the 415–440 eV photon region 1s −→ (1s2s22p2 4P)
np and 1s −→ (1s2s22p2 2P)np resonances forming well-developed Rydberg
series up n = 7 and n = 8 , respectively, were identified in both the single and double ionization
spectra. Theoretical photoionization cross-section calculations, performed using the R-matrix plus
pseudo-states (RMPS) method and the multiconfiguration Dirac-Fock (MCDF) approach were bench
marked against these high-resolution experimental results. Comparison of the state-of-the-art
theoretical work with the experimental studies allowed the identification of new resonance features.
Resonance strengths, energies and Auger widths (where available) are compared quantitatively with
the theoretical values. Contributions from excited metastable states of the N+ ions were carefully
considered throughout
Metadata
Item Type: | Article (Published) |
---|---|
Refereed: | Yes |
Uncontrolled Keywords: | atomic data; inner-shell photoionization; atomic nitrogen ion |
Subjects: | Physical Sciences > Physics |
DCU Faculties and Centres: | DCU Faculties and Schools > Faculty of Science and Health > School of Physical Sciences Research Initiatives and Centres > National Centre for Plasma Science and Technology (NCPST) |
Publisher: | MDPI |
Official URL: | https://doi.org/ |
Copyright Information: | © 2019 The Authors. Open access (CC-BY 4.0) |
ID Code: | 27477 |
Deposited On: | 03 Aug 2022 14:35 by Thomas Murtagh . Last Modified 03 Aug 2022 14:35 |
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