Gallagher, John F. ORCID: 0000-0003-4130-4556, Alley, Steven and Lough, Alan J. (2009) 2-Ferrocenyl-N-(2-ferrocenylbenzoyl)-N-(4-methyl-2-pyridyl)benzamide. Acta Crystallographica Section E, 65 (3). ISSN 1600-5368
Abstract
The title compound, [Fe2(C5H5)2(C30H22N2O2)], a 2:1 product of the reaction of 2-ferrocenylbenzoic acid and 2-amino-4-methylpyridine, forms a twisted molecular structure in the solid state due to steric effects from the two benzene rings ortho-substituted with ferrocenyl and carbonyl-derived groups. A short intramolecular C-H...[pi] interaction is observed involving a substituted [eta]5-C5H4 ring and an ortho H atom of the benzene ring on the opposite side of the molecule. In the crystal structure, there are no classical hydrogen bonds: interactions comprise a short C6-H...[pi](C6) interaction involving substituted benzene rings and two C-H...O=C interactions per molecule.
Metadata
Item Type: | Article (Published) |
---|---|
Refereed: | Yes |
Subjects: | Physical Sciences > Organic chemistry Physical Sciences > Crystallography |
DCU Faculties and Centres: | DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences |
Publisher: | International Union of Crystallography |
Official URL: | http://dx.doi.org/10.1107/S1600536809006278 |
Use License: | This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License |
ID Code: | 2442 |
Deposited On: | 03 Mar 2009 13:58 by DORAS Administrator . Last Modified 10 Oct 2018 11:44 |
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