Walsh, James J. 
ORCID: 0000-0003-4862-8449, Neri, Gaia, Smith, Charlotte L. and Cowan, Alexander J. ORCID: 0000-0001-9032-3548
(2018)
A water-soluble Manganese complex for selective electrocatalytic CO2 reduction to CO.
Organometallics
.
ISSN 0276-7333
Abstract
Relatively few solution electrocatalysts for CO2 reduction in aqueous solutions are
reported. However to be sustainable, electrocatalytic CO2 reduction is likely to be coupled to water
oxidation in a complete device. Here we report a water-soluble Mn polypyridyl complex for the
electrocatalytic reduction of CO2 to CO. This complex shows activity across a broad pH range and an
excellent selectivity at pH 9 (3.8:1, CO:H2). Cyclic voltammetry indicates activity across a range of
different electrode materials (Boron doped diamond, glassy carbon and Hg/Au amalgams).
Metadata
| Item Type: | Article (Published) |
|---|---|
| Refereed: | Yes |
| Subjects: | Physical Sciences > Chemistry Physical Sciences > Electrochemistry Physical Sciences > Environmental chemistry |
| DCU Faculties and Centres: | DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences Research Initiatives and Centres > National Centre for Sensor Research (NCSR) |
| Publisher: | American Chemical Society |
| Official URL: | http://dx.doi.org/10.1021/acs.organomet.8b00336 |
| Copyright Information: | © 2018 American Chemical Society |
| Use License: | This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License |
| Funders: | EPSRC (EP/K006851/1, EP/N010531/1), Science Foundatin Ireland (SFI Grant No. 15/SIRG/3517) |
| ID Code: | 22925 |
| Deposited On: | 16 Jan 2019 10:39 by James Walsh . Last Modified 16 Jan 2019 10:46 |
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