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Facile assembly of polyoxometalate-polyelectrolyte films on nano-MO2 (M = Sn, Ti) for optical applications

Usai, Sara orcid logoORCID: 0000-0002-4254-0051 and Walsh, James J. orcid logoORCID: 0000-0003-4862-8449 (2018) Facile assembly of polyoxometalate-polyelectrolyte films on nano-MO2 (M = Sn, Ti) for optical applications. Journal of Electroanalytical Chemistry, 815 . pp. 86-89. ISSN 1572-6657

Abstract
The polyoxometalate [PMo12O40] 3- (POM) has been deposited onto high surface area nano-SnO2 using a polycation. The POM surface coverage recorded was approximately 17 times higher than that achieved on planar substrates using the same method, reducing considerably the time needed to assemble conducting films suitable for optical applications such as electrochromism. The immobilisation of the analogous tungstate [PW12O40] 3- onto a nano-TiO2 semiconductor electrode demonstrates the versatility of this approach, and underscores potential applications using a large combination of polyoxomolybdates or polyoxotungstates with various metal oxide films.
Metadata
Item Type:Article (Published)
Refereed:Yes
Uncontrolled Keywords:polyoxometalate; self-assembly; nanoparticle, electrochromism; polycation; metal oxide
Subjects:Physical Sciences > Chemistry
Physical Sciences > Electrochemistry
Physical Sciences > Inorganic chemistry
DCU Faculties and Centres:DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences
Research Initiatives and Centres > National Centre for Sensor Research (NCSR)
Publisher:Elsevier
Official URL:https://doi.org/10.1016/j.jelechem.2018.03.007
Copyright Information:© 2018 Elsevier
Use License:This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License
Funders:Science Foundation Ireland (SFI) under the Grant No. 15/SIRG/3517 (JJW), Science Foundation Ireland (SFI) under Grant No. 03/IN.3/1361/EC07
ID Code:22924
Deposited On:16 Jan 2019 10:25 by James Walsh . Last Modified 05 Mar 2020 04:30
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