Walsh, James J. ORCID: 0000-0003-4862-8449, Forster, Mark, Smith, Charlotte L., Neri, Gaia, Potter, Richard J. and Cowan, Alexander J. (2018) Directing the mechanism of CO2 reduction by a Mn catalyst through surface immobilization. Physical Chemistry Chemical Physics, 20 . pp. 6811-6816. ISSN 1463-9076
Abstract
Immobilization of a Mn polypyridyl CO2 reduction electrocatalyst on nanocrystalline TiO2 electrodes
yields an active heterogeneous system and also significantly triggers a change in voltammetric and
catalytic behaviour, relative to in solution. A combination of spectroelectrochemical techniques are
presented here to elucidate the mechanism of the immobilised catalyst in-situ.
Metadata
Item Type: | Article (Published) |
---|---|
Refereed: | Yes |
Subjects: | Physical Sciences > Chemistry Physical Sciences > Electrochemistry |
DCU Faculties and Centres: | DCU Faculties and Schools > Faculty of Science and Health > School of Chemical Sciences Research Initiatives and Centres > National Centre for Sensor Research (NCSR) |
Publisher: | Royal Society of Chemistry |
Official URL: | DOI: 10.1039/C7CP08537K |
Copyright Information: | © 2018 Royal Society of Chemistry |
Use License: | This item is licensed under a Creative Commons Attribution-NonCommercial-Share Alike 3.0 License. View License |
Funders: | Engineering and Physical Sciences Research Council, UK (EP/K006851/1), University of Liverpool |
ID Code: | 22923 |
Deposited On: | 16 Jan 2019 09:50 by James Walsh . Last Modified 20 Feb 2019 04:30 |
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